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Determine the multiplicity and predict the chemical shifts of each signal in the expected 1H NMR spectrum of the following compound. Determine the multiplicity and predict the chemical shifts of each signal in the expected <sup>1</sup>H NMR spectrum of the following compound.

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Predict the chemical shifts for the signals in the 1H NMR spectrum for the following compound. Predict the chemical shifts for the signals in the <sup>1</sup>H NMR spectrum for the following compound.

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List the most common nuclei that are used in NMR.

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A compound, with molecular formula C4H9Br, displays the following 1H NMR and 13C NMR spectra. Propose a structure for this compound. A compound, with molecular formula C<sub>4</sub>H<sub>9</sub>Br, displays the following <sup>1</sup>H NMR and <sup>13</sup>C NMR spectra. Propose a structure for this compound.     A compound, with molecular formula C<sub>4</sub>H<sub>9</sub>Br, displays the following <sup>1</sup>H NMR and <sup>13</sup>C NMR spectra. Propose a structure for this compound.

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Which of the following compounds is consistent with the 13C NMR spectrum shown below? Which of the following compounds is consistent with the <sup>13</sup>C NMR spectrum shown below?     A)  I B)  II C)  III D)  IV E)  V Which of the following compounds is consistent with the <sup>13</sup>C NMR spectrum shown below?     A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) C) and D)
G) A) and E)

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Which of the following is not a common solvent used for acquiring a 1H NMR spectrum?


A) CDCl3
B) CCl4
C) CD3CN
D) CH3OH
E) D2O

F) A) and B)
G) B) and E)

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How many signals would you expect in the 1H NMR spectrum of the following compound? How many signals would you expect in the <sup>1</sup>H NMR spectrum of the following compound?

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Presence of which of the following protons is confirmed by D2O exchange?


A) OH
B) NH2
C) CH
D) A & B
E) none of these

F) A) and B)
G) A) and D)

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Which of the following compounds will display four signals in its 13C NMR spectrum?


A) 2,6-dimethylheptane
B) 2,4-dimethylheptane
C) 3,5-dimethylheptane
D) 4,4-dimethylheptane
E) 3,4-dimethylheptane

F) D) and E)
G) A) and E)

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How many signals would you expect in the 1H NMR spectrum of HOCH2CH2CH2CH2OH?


A) 1
B) 2
C) 3
D) 4
E) 5

F) None of the above
G) A) and B)

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The 1H NMR spectrum of bromoethane shows a signal at 3.5 ppm when the spectrum is recorded using a 60 MHz spectrometer. Where do you expect to see the signal if a 300 MHz instrument is used instead?


A) 3.5 ppm
B) 7.5 ppm
C) 6.8 ppm
D) 5.8 ppm
E) none of these

F) D) and E)
G) A) and B)

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NMR is an abbreviation for ____________ ____________ __________.

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nuclear ma...

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Which of the following compounds will display only three singlets in its 1H NMR spectrum? Which of the following compounds will display only three singlets in its <sup>1</sup>H NMR spectrum?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) A) and D)
G) A) and C)

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Which of the following compounds, with molecular formula C9H18O2, is consistent with the 1H NMR and 13C NMR spectra shown below? SHAPE \* MERGEFORMAT Which of the following compounds, with molecular formula C<sub>9</sub>H<sub>18</sub>O<sub>2</sub>, is consistent with the <sup>1</sup>H NMR and <sup>13</sup>C NMR spectra shown below? SHAPE \* MERGEFORMAT         A)  I B)  II C)  III D)  IV E)  None of these Which of the following compounds, with molecular formula C<sub>9</sub>H<sub>18</sub>O<sub>2</sub>, is consistent with the <sup>1</sup>H NMR and <sup>13</sup>C NMR spectra shown below? SHAPE \* MERGEFORMAT         A)  I B)  II C)  III D)  IV E)  None of these Which of the following compounds, with molecular formula C<sub>9</sub>H<sub>18</sub>O<sub>2</sub>, is consistent with the <sup>1</sup>H NMR and <sup>13</sup>C NMR spectra shown below? SHAPE \* MERGEFORMAT         A)  I B)  II C)  III D)  IV E)  None of these Which of the following compounds, with molecular formula C<sub>9</sub>H<sub>18</sub>O<sub>2</sub>, is consistent with the <sup>1</sup>H NMR and <sup>13</sup>C NMR spectra shown below? SHAPE \* MERGEFORMAT         A)  I B)  II C)  III D)  IV E)  None of these


A) I
B) II
C) III
D) IV
E) None of these

F) B) and C)
G) A) and D)

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Which of the indicated protons in the following compound would appear most upfield in the 1H NMR spectrum? Which of the indicated protons in the following compound would appear most upfield in the <sup>1</sup>H NMR spectrum?   A)  I B)  II C)  III D)  IV E)  I & III


A) I
B) II
C) III
D) IV
E) I & III

F) B) and E)
G) C) and D)

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Draw a structure, with a formula of C5H13N, which has an integration of 9H, 3H, 1H.

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Which of the following carbon atoms will display the signal most downfield in the 13C NMR spectrum? Which of the following carbon atoms will display the signal most downfield in the <sup>13</sup>C NMR spectrum?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) A) and B)
G) A) and C)

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The off-resonance decoupling in 13C NMR allows for ________ splitting.


A) (12C-13C)
B) (12C-1H)
C) (13C-13C)
D) (13C-1H)
E) none of these

F) C) and D)
G) A) and C)

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Which of the following compounds gives a 1H NMR spectrum consisting of only a singlet?


A) 1,1-dichloropropane
B) 1,3-dichloropropane
C) 1,2-dichloropropane
D) 2,2-dichloropropane
E) 1-chloropropane

F) C) and E)
G) B) and D)

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Which of the following is true about the number of signals in a 1H NMR spectrum?


A) it indicates the number of neighboring protons
B) it indicates the electronic environment of neighboring protons
C) it indicates the number of different kinds of protons
D) it indicates the electronic environment of absorbing protons
E) it indicates the number of protons in the signal

F) C) and D)
G) A) and B)

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