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A voltaic cell consists of a Mn/Mn2+ electrode (E° = -1.18 V) and a Fe/Fe2+ electrode (E° = -0.44 V) . Calculate [Fe2+] if [Mn2+] = 0.050 M and Ecell = 0.78 V at 25°C.


A) 0.040 M
B) 0.24 M
C) 1.1 M
D) 1.8 M
E) None of these choices is correct.

F) B) and D)
G) C) and D)

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When the following redox equation is balanced with the smallest whole number coefficients, the coefficient for the hydrogen sulfate ion will be ________. Al(s) + HSO4-(aq) + OH-(aq) → Al2O3(s) + S2-(aq) + H2O(l)


A) 1
B) 3
C) 4
D) 6
E) 8

F) B) and C)
G) A) and E)

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When the following redox equation is balanced with the smallest whole number coefficients, what is the coefficient for nitrogen dioxide? I2(s) + HNO3(aq) → HIO3(aq) + NO2(g) + H2O(l)


A) 1
B) 2
C) 4
D) 5
E) 10

F) B) and D)
G) D) and E)

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When the following redox equation is balanced with the smallest whole number coefficients, what is the coefficient of Sb3+(aq) ? BrO3-(aq) + Sb3+(aq) → Br-(aq) + Sb5+(aq) (acidic solution)


A) 1
B) 2
C) 3
D) 4
E) 6

F) A) and E)
G) A) and D)

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Which is incorrect?


A) At equilibrium, Ecell = 0.
B) E > 0 for a spontaneous process.
C) E = 0 for a spontaneous process.
D) ΔG < 0 for a spontaneous process.
E) ΔG = 0 at equilibrium.

F) A) and E)
G) A) and D)

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Complete and balance the following redox equation. When properly balanced using the smallest whole-number coefficients, the coefficient of S is H2S + HNO3 → S + NO + H2O (acidic solution)


A) 1.
B) 2.
C) 3.
D) 5.
E) 6.

F) A) and B)
G) All of the above

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What is E°cell for the following reaction? Al(s) + 3Ag+(aq) → Al3+(aq) + 3Ag(s) What is E°<sub>cell</sub> for the following reaction? Al(s)  + 3Ag<sup>+</sup>(aq)  → Al<sup>3+</sup>(aq)  + 3Ag(s)    A)  -2.46 V B)  0.86 V C)  -0.86 V D)  2.46 V E)  4.06 V


A) -2.46 V
B) 0.86 V
C) -0.86 V
D) 2.46 V
E) 4.06 V

F) A) and B)
G) A) and C)

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Consider the reaction CuO(s) + H2(g) → Cu(s) + H2O(l) In this reaction, which substances are the oxidizing agent and reducing agent, respectively?


A) CuO and H2
B) H2 and CuO
C) CuO and Cu
D) H2O and H2
E) Cu and H2O

F) A) and B)
G) None of the above

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An electroplating solution is made up of nickel(II) sulfate. How much time would it take to deposit 0.500 g of metallic nickel on a custom car part using a current of 3.00 A?

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9.13 min o...

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What is the name given to the experimental apparatus for generating electricity through the use of a spontaneous redox reaction?


A) Electrolytic cell
B) Galvanic cell
C) Redox cell
D) Cathode
E) Anode

F) D) and E)
G) A) and C)

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What is the name of a galvanic cell that requires a continuous supply of reactants to keep functioning?

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Which metal is not capable of acting as a sacrificial anode when used with iron pipe? Which metal is not capable of acting as a sacrificial anode when used with iron pipe?   A)    B)    C)    D)    E)


A) Which metal is not capable of acting as a sacrificial anode when used with iron pipe?   A)    B)    C)    D)    E)
B) Which metal is not capable of acting as a sacrificial anode when used with iron pipe?   A)    B)    C)    D)    E)
C) Which metal is not capable of acting as a sacrificial anode when used with iron pipe?   A)    B)    C)    D)    E)
D) Which metal is not capable of acting as a sacrificial anode when used with iron pipe?   A)    B)    C)    D)    E)
E) Which metal is not capable of acting as a sacrificial anode when used with iron pipe?   A)    B)    C)    D)    E)

F) D) and E)
G) B) and D)

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Consider the reaction of iodine with manganese dioxide. 3I2(s) + 2MnO2(s) + 8OH-(aq) Consider the reaction of iodine with manganese dioxide. 3I<sub>2</sub>(s)  + 2MnO<sub>2</sub>(s)  + 8OH<sup>-</sup>(aq)    6I<sup>-</sup>(aq)  + 2MnO<sub>4</sub><sup>-</sup>(aq)  + 4H<sub>2</sub>O(l)  The equilibrium constant for the overall reaction is 8.3 × 10<sup>-7</sup>. What is E°<sub>cell</sub> for the reaction at 25°C? (R = 8.314 J/K • mol, F = 96,500 C • mol<sup>-1</sup>)  A)  -0.36 V B)  -0.18 V C)  -0.12 V D)  -0.060 V E)  +0.12 V 6I-(aq) + 2MnO4-(aq) + 4H2O(l) The equilibrium constant for the overall reaction is 8.3 × 10-7. What is E°cell for the reaction at 25°C? (R = 8.314 J/K • mol, F = 96,500 C • mol-1)


A) -0.36 V
B) -0.18 V
C) -0.12 V
D) -0.060 V
E) +0.12 V

F) B) and D)
G) All of the above

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What is E°cell for the reaction of nickel(II) ions with cadmium metal at 25°C? (R = 8.314 J/K • mol, F = 96,500 C • mol -1) What is E°<sub>cell</sub> for the reaction of nickel(II)  ions with cadmium metal at 25°C? (R = 8.314 J/K • mol, F = 96,500 C • mol<sup> -1</sup>)    A)  0.0750 V B)  0.100 V C)  0.120 V D)  0.150 V E)  0.300 V


A) 0.0750 V
B) 0.100 V
C) 0.120 V
D) 0.150 V
E) 0.300 V

F) C) and D)
G) A) and D)

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Which is the Nernst equation?


A) Which is the Nernst equation? A)    B)    C)    D)    E)  None of these statements is correct.
B) Which is the Nernst equation? A)    B)    C)    D)    E)  None of these statements is correct.
C) Which is the Nernst equation? A)    B)    C)    D)    E)  None of these statements is correct.
D) Which is the Nernst equation? A)    B)    C)    D)    E)  None of these statements is correct.
E) None of these statements is correct.

F) All of the above
G) A) and C)

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In a fuel cell, an external source of electrical power is used to drive a nonspontaneous reaction in which a fuel is produced.

A) True
B) False

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A lead-storage battery is not rechargeable.

A) True
B) False

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Predict the products obtained from the electrolysis of a 1 M AlBr3 solution. Predict the products obtained from the electrolysis of a 1 M AlBr<sub>3</sub> solution.   A)  Al and Br<sub>2</sub> B)  Al and O<sub>2</sub> C)  H<sub>2</sub> and O<sub>2</sub> D)  H<sub>2</sub> and Br<sub>2</sub> E)  Al and H<sub>2</sub>


A) Al and Br2
B) Al and O2
C) H2 and O2
D) H2 and Br2
E) Al and H2

F) B) and C)
G) All of the above

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Which electrochemical cell pictured below corresponds to the following cell diagram? Cr(s) | Cr3+(aq, 1.0 M) || Sn2+(aq, 1.0 M) | Sn(s)


A) Which electrochemical cell pictured below corresponds to the following cell diagram? Cr(s)  | Cr<sup>3+</sup>(aq, 1.0 M)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Sn(s)  A)    B)    C)    D)    E)
B) Which electrochemical cell pictured below corresponds to the following cell diagram? Cr(s)  | Cr<sup>3+</sup>(aq, 1.0 M)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Sn(s)  A)    B)    C)    D)    E)
C) Which electrochemical cell pictured below corresponds to the following cell diagram? Cr(s)  | Cr<sup>3+</sup>(aq, 1.0 M)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Sn(s)  A)    B)    C)    D)    E)
D) Which electrochemical cell pictured below corresponds to the following cell diagram? Cr(s)  | Cr<sup>3+</sup>(aq, 1.0 M)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Sn(s)  A)    B)    C)    D)    E)
E) Which electrochemical cell pictured below corresponds to the following cell diagram? Cr(s)  | Cr<sup>3+</sup>(aq, 1.0 M)  || Sn<sup>2+</sup>(aq, 1.0 M)  | Sn(s)  A)    B)    C)    D)    E)

F) All of the above
G) B) and C)

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A current of 250. A flows for 24.0 hours at an anode where the reaction occurring is as follows: Mn2+(aq) + 2H2O(l) → MnO2(s) + 4H+(aq) + 2e- What mass of MnO2 is deposited at this anode?


A) 19.5 kg
B) 12.9 kg
C) 9.73 kg
D) 4.87 kg
E) 2.43 kg

F) C) and D)
G) A) and B)

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